Merkel's CDU is looking most likely to win the most seats in the Bundestag - for the fourth election in a row, The Telegraph reports.
The SPD, led by former President of the European Parliament Martin Schulz, is in second place in the polls - securing around a quarter of the vote, according to The Telegraph.
The AfD - the far-right Alternative for Germany party - had enjoyed a slight rise in the polls in 2016 but have since collapsed into in-fighting and unpopularity.
In reality, the CDU will have to seek a coalition agreement with the SPD or one of the other minor parties to form a government.
It will be clear who has won the election as early as Sunday, when voting ends and the exit poll is released, although it will not be several more weeks until a coalition government is officially agreed.